THIS IS A TEST INSTANCE. Feel free to ask and answer questions, but take care to avoid triggering too many notifications.

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The procedure is described here: https://wiki.wireshark.org/TLS#using-the-pre-master-secret

Make sure your capture contains the TLS handshake, otherwise the decryption will fail.
And the SSLKEYLOGFILE environment needs to be set for the TLS client (browser) or TLS server (web-service).
SSLKEYLOGFILE does not work on libraries that do not support it, like Windows Secure Channel (Schannel).